Enantioselective catalysis; Part 93: Optically active expanded phosphanes derived from 1,2-bisphosphanobenzene and amides and esters of acrylic acid

Article abstract of DOI:10.1055/s-1995-3917

Three new expanded phosphanes were synthesized by reaction of 1,2-bisphosphanobenzene with optically active derivatives of acrylic acid: (R)-(+)-N-methyl-N-(1-phenethyl)acrylamide, (1S,2R,5S)(+)-menthyl acrylate and (1S)-endo-(-)-bornyl acrylate. The thre