Journal of Organometallic Chemistry p. 161 - 168 (1987)
Update date:2022-08-17
Topics:
Casey, Charles P.
Keith Woo
The reaction of the diiron μ-propylidyne complex [(C5H5)(CO)Fe]2(μ-CO)(μ-CCH2CH3)+ PF6- (3) with Me3SiN3 in CD2Cl2 under a CO atmosphere produced 64% (NMR) propanenitrile, 33% [(C5H5)(CO)Fe]2(μ-CO)2 (2) and 16% [(C5H5)(CO)Fe]2(μ-CO)(μ-CCHCH3 (4). Treatment of [(C5H5)(CO)Fe]2(μ-CO)-(μ-C-n-C4H9)+ PF6- (6) under similar conditions produced pentanenitrile in 51% (NMR) yield, 2 in 20% yield and [(C5H5)(CO)Fe]2(μ-CO)(μ-CCHCH2CH2CH3) (7) in 22% yield. Similarly, [(C5H5)(CO)Fe]2(μ-CO)(μ-CC6H4-p-CH3)+ BF4- (5) reacted with Me3SiN3 under a CO atmosphere to produce p-CH3C6H4CN in 64% isolated yield and 2 in 71% isolated yield.
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