Benzimidazolin-2-ylidene complexes of palladium(II) featuring a thioether moiety: Synthesis, characterization, molecular dynamics, and catalytic activities

DOI: 10.1021/om500083r

Source and publish data:

Organometallics p. 1266 - 1275 (2014)

Update date:2022-08-17

Topics:

Authors:

Bernhammer, Jan C.

Huynh, Han Vinh

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Article abstract of DOI:10.1021/om500083r

Six benzimidazolin-2-ylidene palladium(II) complexes with an alkyl-alkyl thioether moiety in the side chain have been synthesized. Due to the hemilabile metal-sulfur bond, the complexes exhibit a marked fluxionality, as evidenced by NMR studies. The thioe

Full text of DOI:10.1021/om500083r

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