Highly enantioselective cyclization using cationic Rh(I) with chiral ligand

DOI: 10.1016/S0040-4039(00)60966-8

Source and publish data:

Tetrahedron Letters p. 6331 - 6334 (1992)

Update date:2022-08-30

Topics:

Authors:

Funakoshi

Sakai Sakai

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Article abstract of DOI:10.1016/S0040-4039(00)60966-8

Highly diastereoselective cyclization (> 99% de) of 3R (or S) 3,4-disubstituted 4-pentenals into the corresponding 3,4-cis(or trans)-disubstituted cyclopentanone and highly enantioselective cyclization (> 99% ee) of 4-substituted 4-pentenals into 3-substi

Full text of DOI:10.1016/S0040-4039(00)60966-8

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