Chemistry Letters p. 1361 - 1364 (1992)
Update date:2022-08-16
Topics:
Nagashima, Hideo
Nakaoka, Akihito
Tajima, Syuji
Saito, Yahachi
Itoh, Kenji
Organopalladium polymers of buckminsterfullerene, C60Pdn, catalyze hydrogenation of olefins and acetylenes at room temperature under a hydrogen atmosphere.The catalytic activity is mainly dependent on the ratio of C60 to Pd in the polymers.Partial hydrogenation of acetylenes is achieved by adding benzylamine as the cocatalyst.
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