Nickel(I)(Salen)-Electrocatalyzed Reduction of Benzal Chloride

DOI: 10.1021/jo00065a008

Source and publish data:

Journal of Organic Chemistry p. 3496 - 3501 (1993)

Update date:2022-08-10

Topics:

Authors:

Fry, Albert J.

Fry, Peter F.

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Article abstract of DOI:10.1021/jo00065a008

Electrochemical reduction of nickel(II)(salen) (5) in the presence of benzal chloride (1) in dimethylformamide at a carbon cathode results in catalytic conversion of 1 into a variety of monomeric and dimeric products, depending upon experimental conditions.The mechanism of formation of the various products and the results of experiments designed to clarify these mechanisms are discussed.

Full text of DOI:10.1021/jo00065a008

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