
Journal of Organic Chemistry p. 5340 - 5343 (1981)
Update date:2022-08-30
Topics:
Savoia, Diego
Tagliavini, Emilio
Trombini, Claudio
Umani-Ronchi, Achille
The reduction of NiBr2*2DME by means of potassium-graphite affords highly dispersed nickel on the graphite surface (Ni-Gr1).Freshly prepared Ni-Gr1 is used "in situ" as a catalyst for semihydrogenation of alkynes to alkenes in the presence of ethylenediamine as catalyst modifier.Unconjugated and conjugated (Z)-alkenes with a stereospecificity of 96-99percent and 94percent, respectively, are obtained.
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