Tetrahedron Letters p. 837 - 840 (1982)
Update date:2022-08-22
Topics:
Chan, T. H.
Li, J. S.
Aida, T.
Harpp, David N.
We have shown that low valent titanium reagents reductively couple α,α'-bis-(trimethylsiloxy) sulfides giving olefines in good yield.With unsymmetrical 1, mixed olefins are obtained suggesting an intermolecular pathway.Finally, we have demonstrated that trans-episulfide 3 is quantitatively converted to trans-stilbene.
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(1980)
