HIGHLY STEREOSPECIFIC THERMOLYSIS OF SPIROOXETANES CONTAINING TETRAHALOGENATED 1,4-BENZOQUINONE MOIETIES

DOI: 10.1016/S0040-4039(00)99267-0

Source and publish data:

Tetrahedron Letters p. 3443 - 3444 (1989)

Update date:2022-08-29

Topics:

Authors:

Oshima, Takumi

Nagai, Toshikazu

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Article abstract of DOI:10.1016/S0040-4039(00)99267-0

Thermolysis of cis- and trans-spirooxetanes (1) proceeded with 94-100percent retention of stereochemistry to give stilbene (2) and quinones (3).Important role of a concerted pathway was assumed.

Full text of DOI:10.1016/S0040-4039(00)99267-0

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