Australian Journal of Chemistry p. 577 - 592 (1995)
Update date:2022-08-11
Topics:
Chai, Christina L. L.
Christen, Detlev
Halton, Brian
Neidlein, Richard
Starr, Malcolm A. E.
The behaviour of 1H-cyclopropabenzene (1) and 1H-cyclopropanaphthalene (23) towards a variety of radicals results in opening of the three-membered ring to give ortho-substituted benzyl and 2-methylnaphthalene derivatives, e.g. (13) and (28), respectively.Ring expansion into the cycloheptatriene manifold by way of addition to the bridge bond and norcaradiene formation have not been observed.Analogous reactions with the methylidenecyclopropanaphthalenes (33) and (34) lead to much decomposition, and provide little evidence for the C 1 cycloproparenyl radicals (35) and (36).
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