INTRAMOLECULAR HYDROSILATION OF ACETYLENES: REGIOSELECTIVE FUNCTIONALIZATION OF HOMOPROPARGYL ALCOHOLS

DOI: 10.1016/S0040-4039(00)88485-3

Source and publish data:

Tetrahedron Letters p. 6955 - 6956 (1988)

Update date:2022-08-29

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Authors:

Tamao, Kohei

Maeda, Kimio

Tanaka, Tetsu

Ito, Yoshihiko

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Article abstract of DOI:10.1016/S0040-4039(00)88485-3

Platinum-catalyzed intramolecular hydrosilation of hydrodimethylsilyl ethers of homopropargyl alcohols proceeds regioselectively in a 5-exo-dig mode.The resulting vinylsilanes can be transformed into 3-alkanon-1-ol and 3-bromo-3-alken-1-ol derivatives by H2O2 oxidation and bromine cleavage, respectively.

Full text of DOI:10.1016/S0040-4039(00)88485-3

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