Preparation and Properties of η3-Allyl(halo)tris(trimethylphosphine)ruthenium(II) Complexes and Their Derivatives

DOI: 10.1246/cl.1994.1041

Source and publish data:

Chemistry Letters p. 1041 - 1044 (1994)

Update date:2022-08-28

Topics:

Authors:

Maruyama, Yooichiroh

Shimizu, Isao

Yamamoto, Akio

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Article abstract of DOI:10.1246/cl.1994.1041

Oxidative addition of allyl halides to Ru(cod)(cot) (cod = 1,5-cyclooctadiene, cot = 1,3,5-cyclooctatriene) in the presence of trimethylphosphine at 50 deg C in benzene gives Ru(η³-allyl)(PMe3)3X (X = Br, Cl), which reacted with PhCHO to yield

Full text of DOI:10.1246/cl.1994.1041

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