Generation of 2-Carboethoxyethylzinc Iodide and 3-Carboethoxypropylzinc Iodide and Their Application to the Synthesis of γ- and δ-Keto Esters

DOI: 10.1016/S0040-4039(01)80887-X

Source and publish data:

Tetrahedron Letters p. 5559 - 5562 (1985)

Update date:2022-08-30

Topics:

Authors:

Tamaru, Yoshinao

Ochiai, Hirofumi

Nakamura, Tatsuya

Tsubaki, Kazunori

Yoshida, Zen-ichi

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Article abstract of DOI:10.1016/S0040-4039(01)80887-X

2-Carboethoxyethylzinc iodide and 3-carboethoxypropylzinc iodide are generated by the reaction of the corresponding iodoesters with Zn-Cu couple and utilized for the palladium catalyzed coupling reaction with acid chloride to quantitatively provide gamma- and delta- keto esters, respectively

Full text of DOI:10.1016/S0040-4039(01)80887-X

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