PREPARATION OF ALKYLBENZENES FROM 1-ALKYLCYCLOHEX-2-ENOLS VIA TRICARBONYLIRON COMPLEXES

DOI: 10.1016/0022-328X(83)80122-3

Source and publish data:

Journal of Organometallic Chemistry p. 243 - 248 (1983)

Update date:2022-08-17

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Authors:

Farcasiu, D.

Marino, Gaye

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Article abstract of DOI:10.1016/0022-328X(83)80122-3

Tertiary cyclohex-2-enols are converted directly to the related tricarbonyl-1,3-cyclohexadieneiron complexes, in good yield.Tricarbonylcyclohexadienyliron salts are conveniently oxidized to the corresponding alkylbenzenes, by cerium(IV) salts.These reactions were incorporated in a procedure of converting the cyclohexenols to aromatics, suitable for the preparation of materials specifically labelled with carbon isotopes.

Full text of DOI:10.1016/0022-328X(83)80122-3

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