Oriental Journal of Chemistry p. 1539 - 1543 (2016)
Update date:2022-08-16
Topics:
Mirtaghizadeh, Mina
Setamdideh, Davood
In this study, we have investigated the selective reduction of aldehydes vs. ketones by NaBH4/PhCO2Na/H2O system under ultrasound irradiation. NaBH4 (1.25 equivalents) and PhCO2Na (2 equivalents) is optimized conditions for reduce a variety of aldehydes (1 mmol) in the presence of ketones (1 mmol) to their corresponding alcohols in water as green solvent in high to excellent yields of the product (90-95%). A benzoate-borane complex [PhCO2-H3B]Na is possibly the active reductant in the reaction mixture.
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