Regioselective Synthesis of Phenols and Halophenols from Arylboronic Acids
FULL PAPERS
complex. The whole mixture was stirred at room tempera-
ture and the reaction was monitored using TLC. When the
starting material was completely consumed, the solid com-
plex was separated by filtration. The filtrate was washed
three times with sodium thiosulfate solution followed by
water. The organic phase was separated and dried over an-
hydrous sodium sulfate. The solvent was evaporated to give
the halophenols in analytically pure form. In some cases, the
halophenols were passed through a flash column using
CH2Cl2 as eluent to separate any impurities present.
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Financial support of our work by the Loker Hydrocarbon
Research Institute, University of Southern California is grate-
fully acknowledged.
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