Tetrahedron Letters p. 1203 - 1206 (1981)
Update date:2022-08-16
Topics:
Adam, Waldemar
Cadiz, Carlos
Mazenod, Francois
Vacuum Flash Pyrolysis (VFP) at ca. 450-500 deg C and ca. 0.1-0.3 Torr of spirocyclic malonyl peroxides (2a,b) affords high yields of allenes (5a,b), while the simple malonyl peroxide (2c) leads to ketone (4), derived respectively from decarboxylation of the intermediary α-lactones (3).
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(1968)Doi:10.1007/BF00470249
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