Enantioselective cyclopropane syntheses using the chiral carbene complexes (SFe)- and (RFe)-C5H5(CO)(PR3)Fe=CHCH 3+. A mechanistic analysis of the carbene transfer reaction

DOI: 10.1021/ja00003a028

Source and publish data:

Journal of the American Chemical Society p. 927 - 939 (1991)

Update date:2022-08-11

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Authors:

Brookhart, Maurice

Liu, Yumin

Goldman, Emma W.

Timmers, Debra A.

Williams, Gregory D.

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Article abstract of DOI:10.1021/ja00003a028

Enantiomerically pure or enriched iron-carbene complexes of the type C₅H₅(CO)(PR₃)Fe=CHCH₃⁺ have been prepared by three routes: (a) Diastereomeric acyl complexes C₅H₅(CO)(PPh View More

Full text of DOI:10.1021/ja00003a028

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