THERMOLYSIS OF N-(o-AZIDOBENZOYL)-IMINOPYRIDINIUM YLIDE: A NEW ROUTE TO 3H-INDAZOL-3-ONE

DOI: 10.1016/S0040-4039(01)80926-6

Source and publish data:

Tetrahedron Letters p. 5707 - 5708 (1985)

Update date:2022-08-16

Topics: Yield Catalyst Decomposition Solvent Thermolysis Synthetic route Rearrangement Chromatography Cyclization Mechanism Intermediate Activation Energy Spectroscopic Analysis Ylide Heterocyclic compound Reactive species Carbonyl Group (C=O)

Authors:

Darwen, Stuart P.

Smalley, Robert K.

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Article abstract of DOI:10.1016/S0040-4039(01)80926-6

3H-Indazol-3-one has been generated by thermolysis of N(o-azidobenzoyl)iminopyridinium ylide, and trapped as its Diels-Alder cycloadducts with several dienes.

Full text of DOI:10.1016/S0040-4039(01)80926-6

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