SYNTHESIS OF 2-SUBSTITUTED 1,3-BUTADIENYL COMPOUNDS BY PALLADIUM-CATALYZED REGIOSELECTIVE 1,2-ELIMINATION REACTION OF METHYLVINYLCARBINOL ACETATES

DOI: 10.1016/S0040-4039(01)81561-6

Source and publish data:

Tetrahedron Letters p. 5193 - 5196 (1984)

Update date:2022-08-30

Topics:

Authors:

Carpita, Adriano

Bonaccorsi, Fabrizio

Rossi, Renzo

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Article abstract of DOI:10.1016/S0040-4039(01)81561-6

Alkylation of the dianion of 3-methyl-3-buten-2-ol, followed by acetylation and palladium-catalyzed 1,2-elimination reaction of the so obtained methylvinylcarbinol acetates allows to synthesize regioselectively 2-substituted 1,3-butadienyl compounds having high isomeric purity.

Full text of DOI:10.1016/S0040-4039(01)81561-6

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