Tetrahedron Letters p. 2915 - 2918 (1996)
Update date:2022-08-10
Topics:
Brough, Paul A.
Fisher, Stephen
Zhao, Baoping
Thomas, Ryan C.
Snieckus, Victor
LDA treatment of 2-silylated benzamides 1 affords 2-fluorosilylated acetophenones 3 in a general process likely driven by CIPE-facilitated α-silyl carbanion formation and rearrangement; oxidation (H2O2) of the products given 2-hydroxyacetophenones and catechols.
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(1969)Doi:10.1021/jm00333a021
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