ASYMMETRIC ALLYLATION OF PROCHIRAL ALDEHYDES WITH A NEW ENANTIOSELECTIVE ALLYLATING AGENT PREPARED FROM STANNOUS TRIFLATE, A CHIRAL DIAMINE, AND ALLYLDIALKYLALUMINIUM

DOI: 10.1246/cl.1986.97

Source and publish data:

Chemistry Letters p. 97 - 100 (1986)

Update date:2022-08-11

Topics:

Authors:

Mukaiyama, Teruaki

Minowa, Nobuto

Oriyama, Takeshi

Narasaka, Koichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1986.97

A new enantioselective allylating agent, prepared by treatment of a mixture of stannous trifluoromethanesulfonate and a chiral diamine with allyldialkylaluminum, reacts with prochiral aldehydes to give secondary homoallyl alcohols in good optical yield.

Full text of DOI:10.1246/cl.1986.97

Products guided by the article

Product name:(S)-1-(4-chlorophenyl)-but-3-en-1-ol

Cas No:104869-96-7

R&D Labs maybe for 104869-96-7

Angel Yeast Co., Ltd.

Contact:+86-717-6370352

Address:168 Chengdong Avenue, Yichang, Hubei 443003, P. R.China
Nanjing distinctions Medical Technology Co., Ltd.(expird)

Contact:+86-15996203785 13914714059

Address:nanjing,jiangsu , China
Chengdu Chengnuo New-Tech Co., Ltd

Contact:0086-028-85749078

Address:4 Jiuyang road,Jiulong industrial port,Chengdu, China
ZHEJIANG JIANYE CHEMICAL CO.,LTD.

Contact:86-571-64149273,64149234

Address:No. 48, Fuxi Road, Meicheng Town
Wuhan Soleado Technology Co.,Ltd.

Contact:86-2783341481 18971291927

Address:RM2405 Unit 1 Builing 1, Taiyin Tower, Changqing Road,Wuhan China

Relevant to this article

Efficient syntheses of imidazolo[1,2-αa]pyridines and -[2,1-α]isoquinolines

Doi:10.1021/jo0012602
(2000)
Amphidinolide L, a New Cytotoxic 27-Membered Macrolide from the Cultured Dinoflagellate Amphidinium sp.

Doi:10.1021/jo00092a045
(1994)
Synthesis of 5-hydroxy-Δ¹-pyrrolines from sec-alkyl aryl ketoximes and acetylene

Doi:10.1016/j.tet.2016.08.088
(2016)
Doi:10.1007/BF01344505
(1900)
Efficient and direct iodination of alkyl benzenes using polymer/HIO4 and I2 under mild condition

Doi:10.4314/bcse.v28i2.15
(2014)
Structurally characterized homo-trinuclear Zn^II and hetero-pentanuclear [ZnII4Ln^III] complexes constructed from an octadentate bis(Salamo)-based ligand: Hirshfeld surfaces, fluorescence and catalytic properties

Doi:10.1039/c9nj00014c
(2019)

Article Doi