ASYMMETRIC ALLYLATION OF PROCHIRAL ALDEHYDES WITH A NEW ENANTIOSELECTIVE ALLYLATING AGENT PREPARED FROM STANNOUS TRIFLATE, A CHIRAL DIAMINE, AND ALLYLDIALKYLALUMINIUM

DOI: 10.1246/cl.1986.97

Source and publish data:

Chemistry Letters p. 97 - 100 (1986)

Update date:2022-08-11

Topics:

Authors:

Mukaiyama, Teruaki

Minowa, Nobuto

Oriyama, Takeshi

Narasaka, Koichi

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Article abstract of DOI:10.1246/cl.1986.97

A new enantioselective allylating agent, prepared by treatment of a mixture of stannous trifluoromethanesulfonate and a chiral diamine with allyldialkylaluminum, reacts with prochiral aldehydes to give secondary homoallyl alcohols in good optical yield.

Full text of DOI:10.1246/cl.1986.97

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