Tetrahedron Letters p. 8985 - 8988 (1997)
Update date:2022-08-11
Topics:
Matsumoto, Takashi
Hamura, Toshiyuki
Kuriyama, Yokusu
Suzuki, Keisuke
In the presence of Li-TMP and an aromatic aldehyde, benzocyclobutenone undergoes an unusual heterolytic C(1)-C(4) bond fission, and subsequent reaction with the aldehyde gives, after acidic workup, isochroman-3-one in high yield.
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Doi:10.3390/molecules24234227
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(2005)Doi:10.1039/c5cc01626f
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