Cp2TiCl2-catalyzed grignard reactions. 2. Reactions with ketones and aldehydes

DOI: 10.1016/S0040-4039(00)78989-1

Source and publish data:

Tetrahedron Letters p. 2171 - 2174 (1980)

Update date:2022-08-10

Topics:

Authors:

Sato, Fumie

Jinbo, Takamasa

Sato, Masao

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)78989-1

The reaction of Grignard reagents with ketones or aldehydes in the presence of a catalytic amount of Cp₂TiCl₂ leads to the corresponding reduction products in high yields. Cp₂TiH intermediate was proposed to account for this observation.

Full text of DOI:10.1016/S0040-4039(00)78989-1

Products guided by the article

Product name:2-METHYL-1-PENTANOL

Cas No:105-30-6

R&D Labs maybe for 105-30-6

LinHai Cina Chemical Co., LTD.

Contact:0576-85580989

Address:Pharma-chem zone,Duqiao,Linhai,Zhejiang,China
Tianjin Ji Ping Jia Chemical Co., Ltd.

Contact:18622448868

Address:tianjin
NingBO Hong Xiang Biochem.Co.Ltd

website:http://www.hxbiochem.com

Contact:0574-66003444

Address:Ning Bo Bei Lun
Xi'an Costrong Pharmaceutical Co., Ltd.

Contact:029- 68576496

Address:Room 2004,Shuibao Building,No.190,South Erhuan Rd, Yanta District,Xi'an,Shaan Xi,China
Chongqing Werlchem Fine Chemical Co. Ltd

Contact:+86-23-67521957

Address:NO.15,Fortune Road,Yubei District,401121,Chongqing,China

Relevant to this article

Doi:10.1021/jo00425a033
()
Enantioselektive Katalyse. VII. Komplexe von (P(R,S),3R,4R,P'(R,S))-3,4-Bis(phenylphosphino)pyrrolidinen. Die Darstellung optisch reiner 1,2-Bisphosphanliganden mit vier Stereozentren, die zusaetzliche funktionelle Gruppen enthalten

Doi:10.1016/0022-328X(89)87286-9
(1989)
Palladium-catalyzed cyclization of alkenyl β-keto esters in the presence of chlorotrimethylsilane

Doi:10.1039/b111644d
(2002)
Synthesis of bicyclic pyrazinones via addition of heterocyclic amines to a nitro-alkene

Doi:10.1016/S0040-4020(01)85023-7
(1994)
Modular diamino- and dioxophosphine oxides and chlorides as ligands for transition-metal-catalyzed C-C and C-N couplings with aryl chlorides

Doi:10.1002/anie.200462371
(2005)
Reactions of <(μ-CO)(μ-RS)Fe2(CO)6> complexes with thiazolyl-, oxazolyl- and imidazolyl-mercurials: a route to Fe2(CO)6 complexes containing an η¹,η²-C=N bridge

Doi:10.1016/0022-328X(93)86080-2
(1993)

Article Doi