Cp2TiCl2-catalyzed grignard reactions. 2. Reactions with ketones and aldehydes

DOI: 10.1016/S0040-4039(00)78989-1

Source and publish data:

Tetrahedron Letters p. 2171 - 2174 (1980)

Update date:2022-08-10

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Authors:

Sato, Fumie

Jinbo, Takamasa

Sato, Masao

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Article abstract of DOI:10.1016/S0040-4039(00)78989-1

The reaction of Grignard reagents with ketones or aldehydes in the presence of a catalytic amount of Cp₂TiCl₂ leads to the corresponding reduction products in high yields. Cp₂TiH intermediate was proposed to account for this observation.

Full text of DOI:10.1016/S0040-4039(00)78989-1

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