Tetrahedron Letters p. 325 - 326 (1990)
Update date:2022-08-11
Topics:
Barton, Derek H. R.
Langlois, Pascal
Okano, Takashi
Ozbalik, Nubar
The reaction of palladium diacetate, triethylamine, ethyl chlorocarbonate and carbon monoxide in acetonitrile at room temperature gives a good yield of diethyl malonate. By 13C labelling of each of the reagents in turn it has been proven that the methylene group of the malonate comes from an acetate originally bonded to PdII.
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Doi:10.1016/0008-6215(90)80111-F
(1990)Doi:10.1002/ejoc.200800941
(2009)Doi:10.1021/jo01074a614
(1960)Doi:10.1080/07328300500208107
(2005)Doi:10.1016/j.poly.2018.07.038
(2018)Doi:10.1021/ic020259d
(2002)
