
Chemistry Letters p. 1649 - 1652 (1983)
Update date:2022-08-10
Topics:
Izumi, Yusuke
Sato, Satoshi
Urabe, Kazuo
The boron trioxide coupled with hydroxyapatite was found to catalyze the Beckmann rearrangement of cyclohexanone oxime in the vapor phase at 300 deg C more selectively than boria-alumina and silica-alumina.The basic property of hydroxyapatite appears to play an important role in effecting the rearrangement selectively.
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