Tetrahedron Letters p. 911 - 914 (1999)
Update date:2022-08-16
Topics:
Hojo, Makoto
Murakami, Chikara
Fujii, Atsuko
Hosomi, Akira
Hydroxy esters are reduced by trimethoxysilane in the presence of a catalytic amount of lithium methoxide to yield diols, while for simple esters the alcohol exchange reaction takes place preferentially. Through the exchange reaction, lactones, without a hydroxy group are reduced. Tosylimines are also reduced in the system.
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