New reactivity of methoxyhydridosilane in the catalytic activation system

DOI: 10.1016/S0040-4039(98)02480-0

Source and publish data:

Tetrahedron Letters p. 911 - 914 (1999)

Update date:2022-08-16

Topics:

Authors:

Hojo, Makoto

Murakami, Chikara

Fujii, Atsuko

Hosomi, Akira

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Article abstract of DOI:10.1016/S0040-4039(98)02480-0

Hydroxy esters are reduced by trimethoxysilane in the presence of a catalytic amount of lithium methoxide to yield diols, while for simple esters the alcohol exchange reaction takes place preferentially. Through the exchange reaction, lactones, without a hydroxy group are reduced. Tosylimines are also reduced in the system.

Full text of DOI:10.1016/S0040-4039(98)02480-0

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