Tetrahedron Letters p. 1501 - 1504 (1980)
Update date:2022-08-16
Topics:
Negishi, Ei-ichi
Yoshida, Tadao
Sterically hindered trialkylalanes, such as triisobutylalane, react with olefins at or below room temperature under the influence of a catalytic amount of Cl2ZrCp2 to effect hydroalumination of the olefins.The reaction can tolerate certain hetero-functional groups, such as OH, SPh and Br, which tend to interfere with previously reported hydroalumination procedures.
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(1946)
