Chemistry Letters p. 699 - 702 (1984)
Update date:2022-08-10
Topics:
Suzuki, Shigeo
Kogai, Katsuhiko
Ono, Yoshio
Palladium dodecatungstophosphate (Pd3(PW12O40)2) supported on silica is an active and selective catalyst for the isomerization of pentane and hexane in the presence of hydrogen.Thus, hexane could be isomerized in a flow system under atmospheric pressure over 90percent selectivity at 483 K.The reaction proceeds in dual-dunctional mechanism; palladium metal formed by the reduction of palladium(II), and protons, act as a hydrogenation-dehydrogenation catalyst and an olefin-isomerization catalyst, respectively.
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