Chemistry Letters p. 573 - 576 (1987)
Update date:2022-08-16
Topics:
Nishimura, Madoka
Askura, Kiyotaka
Iwasawa, Yasuhiro
The new low-valent Nb monomer catalysts which were prepared by taking advantage of the reaction between Nb(ν3-C3H5)4 and surface OH groups on SiO2, Al2O3, or Tio2, followed by the treatments with H2, were found to be active for the hydrogenation of carbon monoxide in which C2-C4 hydrocarbons were mainly produced in the temperature range 423-598 K.In contrast, only the disproportionation reaction of CO to form CO2 proceeded on usual impregnation Nb catalysts and Nb2O5.
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