Chemistry Letters p. 1235 - 1238 (1985)
Update date:2022-08-11
Topics:
Miyashita, Akira
Ikezu, Shohgo
Nohira, Hiroyuki
Irradiation of (ethylene)bis(triphenylphosphine)nickel (1) or bis(triphenylphosphine)nickelacyclopentane induced stereospecific cyclodimerization of substituted olefins such as acrylonitrile and methylacrylate affording trans-1,2-disubstituted cyclobutanes, while 1,7-octadiene was converted to trans-bicyclo<4.2.0>octane.Ethylene was photochemically dimerized to cyclo- and linear dimers induced by 1.
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