Chemistry Letters p. 241 - 244 (1988)
Update date:2022-08-17
Topics:
Maezawa, Akinori
Kane, Hiroshige
Okamoto, Yasuaki
Imanaka, Toshinobu
The thermal stabilities of Mo(CO)6 and subcarbonyl species encaged in a zeolite were found to depend markedly on the Si/Al ratio and cation involved.A highly selective formation of cis-2-butene was observed for the hydrogenation of butadiene over the subcarbonyl species.These thermal and catalytic properties of the carbonyls are correlated to the basicity of the zeolite.
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