Bulletin of the Chemical Society of Japan p. 11 - 16 (1989)
Update date:2022-08-16
Topics:
Maruya, Ken-ichi
Fujisawa, Takeshi
Takasawa, Akihiro
Domen, Kazunari
Onishi, Takaharu
The CO-H2 reaction over ZrO2 was carried out in the presence of various organic additives.The addition of dimethyl ether, methylal, acetaldehyde, and dimethyl acetal showed the marked enhancement effects on the hydrocarbon formation keeping the high selectivity for isobutene.Ethylene was little effective.The addition of acetone, propanal, and propylene resulted in the decrease in the formation of isobutene and the increase in that of n-butenes.The presence of CO and H2 was essential to the selective formation of isobutene.The formation pathways of isobutene and the other hydrocarbons are discussed.
View More
Nanjing Samwon International Limited
Contact:+86-25-84873444
Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
ABA Chemicals (Shanghai) Limited
Contact:021- 5115 9199-232
Address:Suite 18D, #201 Ningxia Road,
website:http://www.sagechem.com
Contact:+86-571-86818502
Address:Room C1301, New Youth Plaza, 8 Jia Shan Road, Hangzhou, China
Jiangxi Hessence Chemicals Co., Ltd.
Contact:+86 796 3511924
Address:Chengxi Industrial Park, Jishui County, Jiangxi Province 331600 China.
Shanghai Pengkai Chemical Co.,Ltd
Contact:+86-21-60526671
Address:No.4226 Duzhuang Rd Minhang District Shanghai China
Doi:10.1016/0022-328X(91)80059-S
(1991)Doi:10.1039/FT9969202211
(1996)Doi:10.1002/ejoc.201800253
(2018)Doi:10.1039/jr9530000483
(1953)Doi:10.1039/c39820000299
(1982)Doi:10.1021/ol026837b
(2002)
