Chemical Communications p. 2039 - 2040 (1996)
Update date:2022-08-11
Topics:
Davies, Sian C.
Henderson, Richard A.
Hughes, David L.
Oglieve, Kay E.
Structurally defined [Mo(η2-MeCCMe)-(Ph2PCH2CH 2PPh2)2] reacts with anhydrous HCl in thf to give predominantly trans-[MoCl2(Ph2PCH2CH2PPh 2)2] with but-1-ene (69 ± 6%) and cis-but-2-ene (10 ± 2%); in addition, some [MoH2Cl2(Ph2PCH2CH 2PPh2)2] and but-2-yne (21 ± 5%) are produced; the mechanistic features by which protonation of an internal alkyne yields a terminal alkene are enumerated.
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