Fluorination with CsSo4F. Part 21. Effect of the structure of alkene and alcohol on stereochemistry and relative rate of fluoroalkoxylation

DOI: 10.1016/S0040-4020(01)89573-9

Source and publish data:

Tetrahedron p. 12235 - 12244 (1994)

Update date:2022-08-11

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Authors:

Stavber, Stojan

Sotler-Pecan, Tjasa

Zupan, Marko

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Article abstract of DOI:10.1016/S0040-4020(01)89573-9

1-Alkoxy-2-fluoro-1-phenyl benzocycloalkanes are efficiently formed by reactions of 1-phenylbenzocycloalkenes with caesium fluoroxysulphate (CFS) in alcohols (MeOH, EtOH, i-PrOH) at room to moderately elevated temperature. The stereochemistry of the react

Full text of DOI:10.1016/S0040-4020(01)89573-9

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