Iridium(I)-catalysed asymmetric hydrosilylation of ketones using a chiral oxazolylferrocene-phosphine hybrid ligand

DOI: 10.1039/cc9960000847

Source and publish data:

Chemical Communications p. 847 - 848 (1996)

Update date:2022-08-11

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Authors:

Nishibayashi, Yoshiaki

Segawa, Kyohei

Takada, Hiroya

Ohe, Kouichi

Uemura, Sakae

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Article abstract of DOI:10.1039/cc9960000847

The chiral oxazolylferrocene-phosphine hybrid ligand (DIPOF) is a very effective ligand for Ir^I-catalysed asymmetric hydrosilylation of simple ketones to give the corresponding sec-alcohols (up to 96% ee) after acid hydrolysis.

Full text of DOI:10.1039/cc9960000847

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