
Journal of Organometallic Chemistry p. 31 - 38 (1988)
Update date:2022-08-16
Topics:
Pons, P.
Biran, C.
Bordeau, M.
Dunogues, J.
Silylation by electroreduction of carbon tetrachloride, chloroform or methylene chloride is more selective than the common organometallic route.Me3SiCCl3 (94percent) and (Me3Si)2Cl2 (68percent) were thus obtained from CCl4, Me3SiCHCl2, (94percent) and (Me3Si)2CHCl (56percent) from CHCl3 and Me3SiCH2Cl (90percent) from CH2Cl2.Complete silylation of polychloromethanes was also successful by electrosynthesis and gave satisfactory yields.
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