ChemCatChem p. 3314 - 3321 (2017)
Update date:2022-08-17
Topics:
Rizescu, Cristina
Podolean, Iunia
Cojocaru, Bogdan
Parvulescu, Vasile I.
Coman, Simona M.
Albero, Josep
Garcia, Hermenegildo
Impregnation of RuCl3 on N-doped graphenes results in the formation of well-dispersed, small ruthenium oxyhydroxide nanoparticles supported on N-doped graphene that may exhibit high selectivity (87 %) for the conversion of glucose into succinic acid under wet oxidation conditions (160 °C, 18 atm O2 pressure). Ruthenium loading and N-atom distribution on graphene influence the catalytic activity, the best performing catalyst having 1 wt. % Ru loading on a graphene having a large population of graphenic N atoms. The high catalytic selectivity to succinic acid was correlated with the presence of small ruthenium nanoparticles. The present catalyst improves the best one previously reported because it does not require the continuous addition of an excess of amine to reach high succinic acid selectivity and reusability.
View MoreShanghai SMEC Trading Co., Ltd.
website:http://www.shanghaismec.com
Contact:+86-21-68811293
Address:ROOM 1101,NO.800 SHANGCHENG RD,SHANGHAI,CHINA
Contact:+86-10-83993285
Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China
Suzhou Jingye Medicine & Chemical Co., Ltd
website:http://www.jingyechem.cn
Contact:+86-512-66658588
Address:No. 88, Sanlian Street, Jinfeng Road, Suzhou New District, Jiangsu Province, P. R. China
Jiangsu Glory Chemical Co., Ltd.
Contact:+86-571-87896791
Address:Yanhua Chemical Park, Hongze, Huai'an, Jiangsu, China
Qingdao S. H. Huanyu Imp. & Exp. Co., Ltd.
Contact:86-532-88250866
Address:Room 615, World Trade Centre Building B, Hongkong Middle Roda 6#, Qingdao, Shandong, China
Doi:10.1515/znb-1980-0719
(1980)Doi:10.1021/acs.inorgchem.0c01744
(2020)Doi:10.1016/j.tet.2014.09.078
(2014)Doi:10.1016/j.molstruc.2020.129002
(2021)Doi:10.1007/s00044-016-1523-0
(2016)Doi:10.1016/j.ejmech.2015.07.033
(2015)