Chemistry Letters p. 584 - 585 (2005)
Update date:2022-08-10
Topics:
Berndt, Torsten
Boege, Olaf
Butadiene, styrene, cyclohexene, allyl acetate, methyl methacrylate, and allyl alcohol were epoxidized in a gas-phase reaction in the absence of a catalyst. The applied oxidizing agent is ozone. With exception of allyl alcohol (selectivity to glycidol: 58%), the selectivity to the corresponding epoxide ranged from 88 to 97%. For acrylonitrile, there was no measureable conversion. Copyright
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