Journal of the Chemical Society. Chemical communications p. 1762 - 1763 (1993)
Update date:2022-08-11
Topics:
Furukawa, Naomichi
Shima, Hidetaka
Kimura, Takeshi
Oxidation of 1,8-bis(allylthio)naphthalene with m-chloroperbenzoic acid (mCPBA) gave the monooxide which undergoes three consecutive sigmatropic rearrangements to afford 2-allylnaphtho<1,8-cd>-1,2-dithiole; the mechanism has been studied using deuterium tracer experiments.
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