Journal of the Chemical Society. Chemical communications p. 667 - 668 (1980)
Update date:2022-08-11
Topics:
Bartok, Mihaly
Notheisz, Ferenc
On the basis of reaction kinetics, H-D exchange, and i.r. studies of the hydrogenolysis of oxirans and oxolans, the opposite regio- and stereo-selectivities of Pt and Ni are interpreted, a new reaction mechanism is proposed, and it is shown experimentally that the reaction mechanism depends inter alia on the steric structure of the molecule.
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