Russian Chemical Bulletin p. 253 - 258 (1998)
Update date:2022-08-29
Topics:
Korsounskii
Matveev
Nazina
Nazin
The primary stage of the decomposition of compounds RN(NO2)CH2C(NO2)2X is the homolytic cleavage of the C - NO2 bond, at X = NO2 and N - NO2 bond at X = F. The inductive effect of substituents decreases the dissociation energies of the C - N and N - N bonds by 1-2 kcal mol-1. Kinetic effects caused by the spatial interaction of groups and by stepwise decomposition of polyfunctional compounds are described.
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