Carbohydrate Research p. 27 - 34 (1980)
Update date:2022-08-10
Topics:
Itano, Kayoko
Yamasaki, Kazuo
Kihara, Chikako
Tanaka, Osamu
Anomeric mono-D-glucosides of optically active trans-1,2-cyclohexanediols <(1R, 2R) and (1S, 2S)> were stereoselectively prepared from the racemic mixture by means of enzymic trans-D-glucosylation using crude enzyme preparations that are commercially available or are utilized for food manufacturing.The (13)C-n.m.r. spectra of these D-glucosides were characterized, and the stereochemical influence, on the glycosylation shifts of cyclohexanol, of the vicinal hydroxyl substitution was discussed in comparison with that of vicinal alkyl substitution reported previously.
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Doi:10.1002/asia.201402779
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(2002)Doi:10.1016/j.apcata.2014.01.057
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(2005)Doi:10.1016/j.carres.2010.09.012
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