Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 1735 - 1756 (1980)
Update date:2022-08-25
Topics:
Amir-Ebrahimi, Valia
Gault, Francois G.
The isomerization, dehydrocyclization and hydrogenolysis of 3-methylhexane have been studied at 320-380 deg C over a series of Pt-Al2O3 catalysts with a metal dispersion extending from 0.05 to 1.The use of five labelled compounds, 3-methyl(1-(13)C), (2-(13)C), (3-(13)C), (6-(13)C)hexanes and 3-methyl((13)C)hexane, alloved distinction between the various parallel pathways.On all catalysts the predominant reaction was the isomerization according to a cyclic mechanism involving either 1,3-dimethyl-, 1,2-dimethyl- or ethyl-cyclopentane intermediates with a relative contribution of 60, 40 and 20 percent, respectively.These results are consistent wiith a dehydrocyclization scheme involving a metallocarbene as precursor and dicarbene or dicarbyne recombination as the rate-determining step.
View MoreContact:+86-0512-62857507
Address:Boji Science Park, No1688C,Taishan road, Suzhou ,China
Weifang Jahwa Chemical Co.,Ltd
Contact:0086-536-8897731,8897730
Address:No.5166 East Dongfeng Street,Weifang,Shandong,China
Jiangsu Zhenfang Chemical CO.,LTD.(Suzhou Zhenfang Chemical Factory)
Contact:+86-512-69598882
Address:Room1201, Jiayuan Road No.1018, Xiangcheng District, Suzhou, China
Xian Changyue Biological Technology Co., Ltd.
website:https://www.xachangyue.com/
Contact:+86-029-62886900
Address:Keji Road NO.70
Contact:+86-10-67147360/67107388
Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
Doi:10.1021/acs.organomet.8b00267
(2018)Doi:10.1016/0040-4039(95)02281-3
(1996)Doi:10.1023/A:1013816422004
(2001)Doi:10.1007/s11172-015-0951-1
(2015)Doi:10.1007/s11172-017-1995-1
(2017)Doi:10.1016/j.tetasy.2004.10.004
(2004)
