FUNCTIONALIZATION OF SATURATED HYDROCARBONS BY MEANS OF APROTIC SUPERACIDS. 1. IONIC BROMINATION OF ALKANES AND CYCLOALKANES

DOI: 10.1007/BF00957779

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1864 - 1868 (1989)

Update date:2022-08-30

Topics:

Authors:

Akhrem, I. S.

Orlinkov, A. V.

Vitt, S. V.

Afanas'eva, L. V.

Vol'pin, M. E.

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Article abstract of DOI:10.1007/BF00957779

Aprotic organic superacids with the composition AcBr*2AlX3 (X = Cl, Br) are efficient catalysts (Cat) for the bromination of n-alkanes and cycloalkanes by molecular bromine.Under the given conditions, the reactions afford (predominantly or exclusively) monobromides in high yields.

Full text of DOI:10.1007/BF00957779

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