The insertion of sulfur into the non-activated C - H bond a possible model for penicillin cyclase and biotin synthase

DOI: 10.1016/S0040-4039(00)79921-7

Source and publish data:

Tetrahedron Letters p. 2351 - 2354 (1991)

Update date:2022-08-11

Topics:

Authors:

Balavoine, Gilbert

Barton, Derek H. R.

Gref, Aurore

Lellouche, Isabelle

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Article abstract of DOI:10.1016/S0040-4039(00)79921-7

When cyclohexane is subjected to Gif-type oxidation conditions in the presence of sufficient H₂S, Na₂S or (in Gif^III) S₈, the normal oxidation process is replaced by the formation of dicyclohexyl di- and polysulfides.

Full text of DOI:10.1016/S0040-4039(00)79921-7

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