Rh(I) COMPLEXES CONTAINING FULLY ALKYLATED MONO- AND DIPHOSPHINE LIGANDS AS HIGHLY ACTIVE HYDROGENATION CATALYSTS FOR CARBONYL COMPOUNDS

DOI: 10.1246/cl.1982.261

Source and publish data:

Chemistry Letters p. 261 - 264 (1982)

Update date:2022-08-11

Topics:

Authors:

Tani, Kazuhide

Suwa, Kenichi

Tanigawa, Eiji

Yoshida, Toshikatsu

Okano, Tamon

Otsuka, Sei

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1982.261

Our search for highly active hydrogenation catalysts for carbonyl compounds, starting with neutral Rh(I) hydride complexes, (R=i-Pr, n=3; R=Cy, n=2), has led to the discovery of cationic Rh(I) complexes with fully alkylated diphosphine ligands, ClO4 (n=3,4).These compounds prove to be versatile and efficient for hydrogenation of a variety of carbonyl compounds, including aldehydes.

Full text of DOI:10.1246/cl.1982.261

Products guided by the article

Product name:Cyclohexanol

Cas No:108-93-0

R&D Labs maybe for 108-93-0

Anhui Charm Imp.&Exp.Co., Ltd

website:http://www.chinacharm.cn/

Contact:86 551 5316260

Address:No. 211,XiangZhang Road,Hefei City,Anhui Province,China
zhuzhou zhongle chemical co. ltd.

Contact:+86-0731 28228409

Address:Zhuzhou, Hunan, China
Xi'an Tizan Tech & Industry Co., Ltd.

Contact:86-18629066522

Address:C3009 TANG FENG INTERNATIONAL PLAZA, NO.18 FENGHUI NAN ROAD, XI'AN HIGH TECH ZONE, 710075 CHINA.
Eastar Chemical Corporation

website:http://www.eastarchem.com/

Contact:1-800-898-2436

Address:1215 K Street, STE 1700
Jiangyin Tenghua Import&Export Co.,Ltd.

Contact:+86-510-86263875

Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China

Relevant to this article

A supramolecular hydrogelator of curcumin

Doi:10.1039/c4cc03139c
(2014)
Light-Regulated Molecular Trafficking in a Synthetic Water-Soluble Host

Doi:10.1021/jacs.5b11642
(2016)
Doi:10.1139/v53-042
(1953)
Synthesis of Isoindolo[2,1-a]quinazoline, Isoindolo[2,1-a]pyrrolo [2,1-c]quinoxalinone, and Indolo[1,2-a]isoindolo[1,2-c]quinoxalinone Derivatives in a Deep Eutectic Solvent

Doi:10.1055/s-0036-1588074
(2016)
Chiral molybdenum(VI) complexes with tridentate Schiff bases derived from S(+)-1-amino-2-propanol: Synthesis, characterization and catalytic activity in the oxidation of prochiral sulfides and olefins

Doi:10.1016/j.poly.2016.06.015
(2016)
Oxidation kinetics of ferrocene derivatives with dibenzoyl peroxide

Doi:10.1016/j.jorganchem.2018.10.022
(2019)

Article Doi