Rh(I) COMPLEXES CONTAINING FULLY ALKYLATED MONO- AND DIPHOSPHINE LIGANDS AS HIGHLY ACTIVE HYDROGENATION CATALYSTS FOR CARBONYL COMPOUNDS

DOI: 10.1246/cl.1982.261

Source and publish data:

Chemistry Letters p. 261 - 264 (1982)

Update date:2022-08-11

Topics:

Authors:

Tani, Kazuhide

Suwa, Kenichi

Tanigawa, Eiji

Yoshida, Toshikatsu

Okano, Tamon

Otsuka, Sei

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Article abstract of DOI:10.1246/cl.1982.261

Our search for highly active hydrogenation catalysts for carbonyl compounds, starting with neutral Rh(I) hydride complexes, (R=i-Pr, n=3; R=Cy, n=2), has led to the discovery of cationic Rh(I) complexes with fully alkylated diphosphine ligands, ClO4 (n=3,4).These compounds prove to be versatile and efficient for hydrogenation of a variety of carbonyl compounds, including aldehydes.

Full text of DOI:10.1246/cl.1982.261

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