186. Steric Effects on Reaction Rates. Rate and Equilibrium Constants for Oxidation of Cyclanols

DOI: 10.1002/hlca.19800630702

Source and publish data:

Helvetica Chimica Acta p. 1759 - 1766 (1980)

Update date:2022-08-18

Topics:

Authors:

Paul, Mueller

Blanc, Jacky

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19800630702

Equilibrium constants for oxidations of cyclanols by cyclohexanone in benzene have been determined in the presence of aluminium isopropoxide.The free energies of the equilibrium (ΔG_ox) are correlated with equilibrium constants for dissociation of cyanohydrins, rate constants for cyclanol oxidation with chromic acid, ketone reduction with sodium borohydride and trifluoroethanolysis of tosylates.

Full text of DOI:10.1002/hlca.19800630702

Products guided by the article

Product name:Cyclohexanol

Cas No:108-93-0

R&D Labs maybe for 108-93-0

Huangshan Honghui Pharm Technology Co., Ltd.(expird)

website:http://www.honghuichem.com

Contact:18855958372

Address:Qingshan Wan No.1,Nanyuan Kou,SheXian Huangshan City,Anhui Province
Huaihua Baohua Biotechnology Co.,Ltd

website:http://www.baochengchem.com

Contact:86-519-82698291

Address:HouYang chemical development zone,Jintan,Jiangsu,China (213200)
Xiamen XM-Innovation Chemical Co., Ltd

Contact:+86-592-3216205

Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C
Shanghai Pengkai Chemical Co.,Ltd

Contact:+86-21-60526671

Address:No.4226 Duzhuang Rd Minhang District Shanghai China
Engineering Research Center of Pesticide, Heilongjiang Province

Contact:+86-451-86609001

Address:No.74 of Xuefu Road, Nangang District,

Relevant to this article

Pyridine-free and solvent-free acetylation of nucleosides promoted by molecular sieves

Doi:10.1055/s-2006-958430
(2006)
Synthesis of phthalocyanine fused with bicyclo[2.2.2]octadienes and thermal conversion into naphthalocyanine

Doi:10.3987/com-07-s(w)75
(2007)
Regioselective Synthesis of Isomeric 3-[1-Substituted Pyrazol-3(5)-yl]indoles from β-Ethylthio-β-indolyl-α,β-unsaturated Ketones

Doi:10.1055/s-0040-1707999
(2020)
Synthesis of 2-Acetyl-4-(1,2,3,4-tetrahydroxybutyl)imidazole

Doi:10.1021/jo00207a048
(1985)
Evaluated kinetics of the reactions of H and CH₃ with n-alkanes: Experiments with n-butane and a combustion model reaction network analysis

Doi:10.1021/acs.jpca.5b01004
(2015)
METHYLIDYNE TRICOBALT NONACARBONYL CLUSTERS; OPTICALLY ACTIVE SILICON AND GERMANIUM DERIVATIVES, AND SUBSTITUTIONS AT SILICON

Doi:10.1016/S0022-328X(00)88366-7
(1981)

Article Doi