186. Steric Effects on Reaction Rates. Rate and Equilibrium Constants for Oxidation of Cyclanols

DOI: 10.1002/hlca.19800630702

Source and publish data:

Helvetica Chimica Acta p. 1759 - 1766 (1980)

Update date:2022-08-18

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Authors:

Paul, Mueller

Blanc, Jacky

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Article abstract of DOI:10.1002/hlca.19800630702

Equilibrium constants for oxidations of cyclanols by cyclohexanone in benzene have been determined in the presence of aluminium isopropoxide.The free energies of the equilibrium (ΔG_ox) are correlated with equilibrium constants for dissociation of cyanohydrins, rate constants for cyclanol oxidation with chromic acid, ketone reduction with sodium borohydride and trifluoroethanolysis of tosylates.

Full text of DOI:10.1002/hlca.19800630702

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