METHYLIDYNE TRICOBALT NONACARBONYL CLUSTERS; OPTICALLY ACTIVE SILICON AND GERMANIUM DERIVATIVES, AND SUBSTITUTIONS AT SILICON

DOI: 10.1016/S0022-328X(00)88366-7

Source and publish data:

Journal of Organometallic Chemistry p. 257 - 270 (1981)

Update date:2022-08-18

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Authors:

Combes, Christian E. J.

Corriu, Robert J. P.

Henner, Bernard J. L.

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Article abstract of DOI:10.1016/S0022-328X(00)88366-7

The preparation and alcoholysis of chiral chlorosilanes containing the noncarbonyltricobaltcarbon cluster, RR'Si(Cl)CCo3(CO)9, is described.The alkoxy derivatives react with i-Bu2AlH or BF3*Et2O to give the corresponding silicon hydride or fluoride.Reacti

Full text of DOI:10.1016/S0022-328X(00)88366-7

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