Journal of the Chemical Society. Chemical communications p. 341 - 343 (1986)
Update date:2022-08-30
Topics:
Battioni, Pierrette
Renaud, Jean-Paul
Bartoli, Jean Francois
Mansuy, Daniel
High conversions of alkanes into alcohols and ketones were obtained by using H2O2 as an oxidizing agent and a Mn-porphyrin as the catalyst in the presence of imidazole; yields between 40 and 85percent for oxidation of cyclohexane, cyclo-octane, adamantane, and various compounds containing a benzylic C-H bond by diluted aqueous H2O2 were obtained within 2 h at 29 deg C without significant destruction of the catalyst.
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